Police were tracking the driver from above and the suspect kept driving around Mesa.
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DPS says a drivers whose vehicle had already been hit several times got out of the car in the middle of the roadway.
DPS says it was a serious injury crash but the injuries were non-life threatening.
The freeway is at a standstill as officials are investigate.
This is the second time Dorfman has been arrested for shooting at another driver according to court documents.
Two people were arrested while a third ran off.
The right lane of the US-60 westbound will remain closed as DPS continues to investigate.
The driver, 34-year-old Adolfo Veliz, and 23-year-old Miguel Rodriguez, both from Phoenix, were arrested and booked into the Pima County jail on felony charges.
PHOENIX (3TV/CBS 5) -- One person was killed in a crash on the Interstate 10 near the I-17 split, according to the Department of Public Safety.